Хімія, фізика та технологія поверхні, 2017, 8 (2), 203-213.

Іммобілізація орто-тіокарборану на нанокомпозитах магнетиту, допованих оксидом гадолінію



DOI: https://doi.org/10.15407/hftp08.02.203

A. L. Petranovska, Ie. V. Pylypchuk, P. P. Gorbyk, O. M. Korduban

Анотація


Запропоновано спосіб іммобілізації орто-тіокарборану (С2В10Н11-SH) на поверхні нанокомпозитів складу Fe3O4/Gd2O3 за реакцією тіол-дисульфідного обміну. Для одержання вільних -SH груп поверхня нанокомпозитів Fe3O4/Gd2O3 попередньо модифікувалась мезо-2,3-димеркаптосукциновою кислотою. Встановлено число реакційноздатних тіольних груп на поверхні нанокомпозитів, а також кількість іммобілізованого орто-тіокарборану. Структуру синтезованих нанокомпозитів підтверджено комплексом фізико-хімічних методів аналізу. 


Ключові слова


нейтронозахватний агент; магнетит; гадоліній; карборан; модифікування; біосумісні покриття; B- та Gd-вмісні наноматеріали

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Посилання


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DOI: https://doi.org/10.15407/hftp08.02.203

Copyright (©) 2017 A. L. Petranovska, Ie. V. Pylypchuk, P. P. Gorbyk, O. M. Korduban

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