Ion-Exchange Properties of Modified Silica with Bound Amides of Polyhexamethyleneguanidine and Maleic or o-Phthalic Acids

Authors

  • A. D. Dadashev Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine
  • V. A. Tertykh Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine
  • E. S. Yanovska Taras Shevchenko National University of Kyiv
  • K. V. Yanova Ukrainian State University of Chemical Technology

Abstract

Amides of polyhexamethyleneguanidine and maleic or o-phthalic acids were chemically bound with the silica surface. Adsorption properties of synthesized modified silicas have been studied with respect to V(V)-, Cr(VI)-, Mo(VI)-, and W(VI)-containing anions. Both of adsorbents were found to show high adsorption activity in the acidic and slightly acidic media. Kinetic parameters of the obtained composites are closely similar to a polymeric adsorbent. Reduction of Mo(VI) and Cr(VI) ions was detected at adsorption on silica with bound amide of polyhexamethyleneguanidine and o-phthalic acid. The investigation demonstrates the possibility of the quantitative determination of microamounts of the studied metals in the adsorbent phase using the X-ray-fluorescence analysis after extraction of anions from a solution.

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(1)
Dadashev, A. D.; Tertykh, V. A.; Yanovska, E. S.; Yanova, K. V. Ion-Exchange Properties of Modified Silica With Bound Amides of Polyhexamethyleneguanidine and Maleic or O-Phthalic Acids. Him. Fiz. Tehnol. Poverhni 2012, 3, 419-428.

Issue

Vol. 3 No. 4 (2012): Chemistry, Physics and Technology of Surface / Himia, Fizika ta Tehnologia Poverhni

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