Natural Clinoptilolite Modified with Manganese (II) Chloride in the Reaction of Ozone Decomposition

Authors

  • T. L. Rakitskaya Mechnickov National University of Odessa
  • A. S. Truba Mechnickov National University of Odessa
  • L. A. Raskola Mechnickov National University of Odessa
  • A. A. Ennan Physicochemical Institute of Environment and Human Protection

Keywords:

clinoptilolite, manganese (II) chloride, impregnation, ozone decomposition, X-ray analysis

Abstract

Samples of clinoptilolite modified with manganese(II) chloride (MnCl2/N-CLI) have been obtained by incipient wetness impregnation method with subsequent drying at 110°C until constant weight. Natural clinoptilolite and MnCl2/N-CLI samples have been characterized by X-ray method and tested in the reaction of low-temperature ozone decomposition. Dependent on occupancy of clinoptilolite surface by manganese(II) chloride, manganese (II) complexes with various composition and activity are formed.

References

1. Тарасевич Ю.И. Природные сорбенты в процессе очистки вод. – Киев: Наукова думка, 1981. – 208 с.

2. Nagendrappa G. Organic synthesis using clay and clay-supported catalysts // Appl. Clay Sci. – 2011. – V. 53, N 2. – P. 106–138.

3. Zhou C.H. An overview on strategies towards clay-based designer catalysts for green and sustainable catalysis // Appl. Clay Sci. – 2011. – V. 53, N 2. – P. 87–96.

4. Бражник Д.В., Зажигалов В.А., Григорян Р.Р. и др. Использование природных цеолитов для создания катализаторов нейтрализа-ции газовых выбросов // Энерготехноло-гии и ресурсосбережение. – 2009. – № 1. – С. 27–32.

5. Garriazo J.G., Martinez L.M., Odriozola J.A. et al. Gold supported on Fe, Ce, and pillared bentonites for CO oxidation reaction // Appl. Catal. B: Environ. – 2007. – V. 72, N 1–2. – P. 157–165.

6. Rhodes C.N., Brown D. R. Surface properties and porosities of silica and acid-treated montmorillonite catalyst supports: influence on activities of supported ZnCl2 alkylation catalysts // J. Chem. Soc. Faraday Trans. – 1993. – V. 89, N 9. – P.1387-1391.

7. Ракитская Т.Л., Киосе Т.А., Волкова В.Я., Эннан А.А. Использование природных алюмосиликатов Украины для разработки новых металлокомплексных катализаторов очистки воздуха от газообразных токсичных веществ // Энерготехнологии и ресурсосбе-режение. – 2009. – № 6. – С. 18–23.

8. Rakitskaya T.L., Kiose T.A., Vasylechko V.O. et al. Adsorption-desorption properties of clinoptilolites and the catalytic activity of surface Cu(II)-Pd(II) complexes in the reaction of carbon monoxide oxidation with oxygen // Chem. of Metals of Alloys. – 2011. – V. 4, N 3–4. – P. 213–218.

9. Ракитская Т.Л., Раскола Л.А., Труба А.С. и др. Каталитическое разложение озона закрепленными на природном клиноптило-лите ацидокомплексами кобальта (II) // Вопросы химии и химической технологии. – 2011. – № 2. – С. 118–123.

10. Oyama S.T. Chemical and catalytic properties of ozone // Catal. Rev. – 2000. – V. 42, N 3. – P. 279–322.

11. Rakitskaya T.L., Bandurko A.Yu., Ennan A.A. et al. Low-temperature catalytic decomposition of ozone microconcentrations by carbon fibrous materials // Advances Environ. Reserch. – 2000. – V. 3, N 4. – P. 472–487.

12. Treacy M.N.J., Higgins J.B. Collection of simulated XRD powder patterns for zeolites. – Amsterdam: Elsevier, 2001. – 586 c.

13. Миркин Л.И. Справочник по рентгено-структурному анализу поликристаллов. – Москва: Физматиздат, 1960. – 326 с.

14. Korkuna O., Leboda R, Skubiszewska-Zieba J. et al. Structural and physicochemical properties of natural zeolites: clinoptilolite and mordenite // Micropor. Mesopor. Mater. – 2006. – V. 87, N 3. – Р. 243–254.

15. Ракитская Т.Л., Раскола Л.А., Киосе Т.А. и др. Адсорбция ионов 3d-металлов природным и кислотно-модифициро-ванным клиноптилолитом // Вісн. Одеськ. нац. ун-ту. Хімія. – 2010. – Т. 15, вип. 3. – С. 85–91.

16. Doula M.K., Ioannou A. The effect of electrolyte anion on Cu adsorption–desorption by clinoptilolite // Micropor. Mesopor. Mater. – 2003. – V. 58, N 2. – P. 115-130.

17. Ракитская Т.Л., Эннан А.А. Фосфин. Физико-химические свойства и практические аспекты улавливания: монография. – Одесса: Астропринт, 2012. – 208 с.

Downloads

How to Cite

(1)
Rakitskaya, T. L.; Truba, A. S.; Raskola, L. A.; Ennan, A. A. Natural Clinoptilolite Modified With Manganese (II) Chloride in the Reaction of Ozone Decomposition. Him. Fiz. Tehnol. Poverhni 2013, 4, 297-304.

Issue

Vol. 4 No. 3 (2013): Chemistry, Physics and Technology of Surface / Himia, Fizika ta Tehnologia Poverhni

Section

Articles

License

  1. Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
  2. Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
  3. Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work.