Compensation Effect on Cu-Co-Fe Oxide Catalysts of CO Oxidation

Authors

  • O. Byeda Shevchenko Kyiv National University
  • E. Ischenko Shevchenko Kyiv National University
  • V. Yatsimirsk Shevchenko Kyiv National University

Abstract

The occurrence of compensation effect on massive and supported oxide catalysts of CO oxidation is shown. The explanation of compensation effect is offered based on the data on the surface state of the catalysts that are obtained by means of thermally programmed desorption method with mass spectrometric registration of the desorbed particles (TPD MS).

References

Kemball C. The reaction of methane and deuterium on evaporated nickel catalysts // Proc. Roy. Soc. London, A. – 1951. – V. 207. – P. 539–554.

Yatsimirsky V.K. The interrelationship between energy and entropy as a possible cause of the compensation effect // Theor. Exp. chem. – 1977. – V. 12, N 4. – P. 443‑446.

Kiperman S.L. Introduction to Kinetics of Heterogeneous Catalytic Reactions. – Мoscow: Nauka, 1964. – 607 p. (in Russian).

Galwey A.K. Compensation effect in heterogeneous catalysis // Adv. Catal. – 1977. – V. 26. – P. 247–307.

Morooka Y., Ozaki, A. Regularities in catalytic properties of metal oxides in propylene oxidation // J. Catal. – 1966. – V.5, N 1. – P. 116–124.

Golodets G.I., Goncharuk V.V., Roiter V.A. "Compensation effect" in heterogeneous catalysis.// Theor. Exp. Chem. – 1972. – V. 5, N 2. – P. 132–137.

Yatsimirsky V.K., Ischenko E.V., Boldyreva N.A. et al. Catalytic activity in CO oxidation and adsorption characteristics of Fe–Co oxide system // Theor. Exp. Chem. – 2001.–V. 37, N 5. – P. 315–318.

Yatsimirsky V.K., Boldyreva N.A., Ischenko E.V. et al. State of the surface of Cu-Co oxide system in the reaction of CO oxidation // Bulletin of Donetsk University. A. Natural sciences. – 2002. – N 2. – P. 242–246. (in Ukrainian).

Yatsimirsky V.K., Ischenko E.V., Philippova L.V. Kinetics of CO oxidation over Fe-Cu oxide samples // Bulletin of Kyiv University, Chemistry. – 2003. – V. 40. – P. 81–83. (in Ukrainian).

Yatsimirsky V.K., Ischenko E.V., Mischanchuk B.G., Philippova L.V. Catalytic activity and state of the surface of Fe-Mn oxide system in the reaction of CO oxidation // Ukrainian Chemical Journal. – 2003. – V. 69, N 7. – P. 15–18. (in Ukrainian).

Yatsimirsky V.K., Ischenko E.V., Gayday S.V. State of the surface of Fe-Co-Cu oxide system in the reaction of CO oxidation // Ukrainian Chemistry Journal. – 2003. – V. 69, N 4. – P. 98–100. (in Ukrainian).

Yatsimirsky V.K., Maksimov Yu.V., Suzdalev I.P. et al. Physical and chemical properties and activity of Fe–Co–Cu oxide catalysts in oxidation of CO // Theor. Exp. Chem.–2003. – V. 39, N 3. – P. 190–194.

Yatsimirsky V.K., Ischenko E.V., Gayday S.V., Tsapjuk G.G. Kinetic peculiarities of CO oxidation over oxide Fe-Co-Cu catalyst and Co2O3 // Reports of NAS of Ukraine. – 2003. – N 9. – P. 156–160. (in Ukrainian).

Ischenko E.V., Matzui L.Yu., Gayday S.V. et al. Thermo-exfoliated graphite containing CuO/Cu2(OH)3NO3:(Co2+/Fe3+) composites: preparation, characterization and catalytic performance in CO conversion // Materials. – 2010. – N 3. – P. 572–584.

Ischenko E.V., Byeda A.А., Diyuk V.E. et al. Activated carbon, modified by maleic anhydride, as a support for the oxide catalysts of CO oxidation // Ukrainian Chemical Journal. – 2009. – V. 75, N 5, – P. 23–25. (in Ukrainian).

Yatsimirsky V.K., Ischenko E.V., Gayday S.V. et al. Oxide Cu-Co-Fe catalysts supported on the oxidized FAC in the reaction of CO oxidation // Ukrainian Chemical Journal. – 2009. – V. 75, N 6. – P. 91–94. (in Ukrainian).

Ischenko E.V., Dyachenko A.G., Yatsimirsky A.V. et al. SiO2 as a support for oxide Cu-Co-Fe catalysts of CO oxidation reaction // Ukrainian Chemical Journal. – 2008. – V. 74, N 4. – P. 85–87. (in Ukrainian).

Ischenko E.V., Sylenko P.M., Shkoda T.М. et al. Oxide Cu-Co-Fe catalyst of CO oxidation supported on silicon carbide nanofibers // Chemistry, Physics and Technology of Surface. – 2009. – N 15. – P. 279–283.

Ischenko E.V., Sylenko P.M., Zakharova Т.М. et al. Cu2(OH)3NO3 supported on SiC as active catalyst of CO oxidation // Catalysis and Oil Chemistry. – 2009. – N 17. – P. 18–21. (in Ukrainian).

Ischenko E.V., Yatsimirsky V.K., Dyache­nko A.G. et al. Cu-Co-Fe oxide catalysts supported on carbon nanotubes for the oxidation of CO // Theor.Exp. Chem. – 2006. – v. 42, N 4.– P. 229-233.

Ischenko E.V., Yatsimirsky V.K., Dyachen­ko A.G. et al. Cu-Co-Fe oxide catalysts supported on carbon nanotubes in the reaction of CO oxidation // Polish Journal of Chemistry. – 2008. – V. 82. – P. 291–297.

Ischenko E.V., Yatsimirsky V.K., Byeda A.А. et al Ternary Cu-Co-Fe oxide catalysts of carbon monoxide oxidation supported on carbon nanotubes // Modern problems of Physical Chemistry: IV Intern. Conf. (31 Aug. – 03 Sept., 2009,. – P. 79. Donetsk, Ukraine)

Byeda A.А., Ischenko E.V., Gayday S.V. Application of mass spectrometric studies for determination of the surface state of heterogeneous catalysts // Bulletin of Kyiv University, Chemistry. – 2008. – V. 49. – P. 48–52. (in Ukrainian).

Krylov О.V., Kiselev V.F. Adsorption and catalysis over transition metals and their oxides. Moscow: Khimia, 1981.– 423 p. (in Russian).

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(1)
Byeda, O.; Ischenko, E.; Yatsimirsk, V. Compensation Effect on Cu-Co-Fe Oxide Catalysts of CO Oxidation. Him. Fiz. Tehnol. Poverhni 2010, 1, 228-234.