Enhancement of the Hydrogen Sorption on Mesoporous Carbon by Doping with Palladium Nanoparticles

Authors

  • V. Gerda Université Pierre and Marie Curie
  • G. M. Telbiz Pysarzhevskiy Institute of Physical Chemistry of National Academy of Sciences of Ukraine
  • N. Kobylinskaya Taras Shevchenko National University of Kyiv
  • V. N. Zaitsev Taras Shevchenko National University of Kyiv
  • P. A. Manorik Pysarzhevskiy Institute of Physical Chemistry of National Academy of Sciences of Ukraine
  • J. Fraissard Université Pierre and Marie Curie

Abstract

We have used the matrix synthesis protocol of Ryoo et al. for the preparation of highly ordered cubic mesoporous carbon (CMK-1) using mesoporous silica (MCM-48) as a template, in order to prepare palladium-doped CMK-1. The carbon obtained has a high surface area of 1800 m2g-1, a large porous volume of 1.14 cm3g-1 and average pore diameter of 3.03 nm. Step-by-step formation of mesoporous carbon was followed by X-ray diffraction, FTIR, N2 adsorption desorption and TPD mass-spectrometry. The physical data of CMK-1 are hardly changed by Pd incorporation (CMK?1/Pd). Transmission electron microscopy and Raman spectroscopy show that the framework of the highly ordered mesoporous carbon/Pd consists of an aligned carbon phase with a graphite mode region. The potential application of CMK-1 and CMK?1/Pd as sorbents for hydrogen storage is discussed.

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How to Cite

(1)
Gerda, V.; Telbiz, G. M.; Kobylinskaya, N.; Zaitsev, V. N.; Manorik, P. A.; Fraissard, J. Enhancement of the Hydrogen Sorption on Mesoporous Carbon by Doping With Palladium Nanoparticles. Him. Fiz. Tehnol. Poverhni 2010, 1, 315-320.

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Vol. 1 No. 3 (2010): Chemistry, Physics and Technology of Surface / Himia, Fizika ta Tehnologia Poverhni

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