Chemistry, Physics and Technology of Surface, 2012, 3 (4), 375-385.

New Nanoporous β-Cyclodextrin-Containing Silicas for Sorption of Heavy Metal Nitrates



L. A. Belyakova, O. M. Shvets, D. Yu. Lyashenko

Abstract


Nanoporous b-cyclodextrin-containing silicas, which differ by functional substituents of the wide edge of attached cyclic oligosaccharide molecules, were synthesized. Formation of the supramolecular structures (supermolecules), which chemical composition depends on the nature of adsorbed cations and functional substituents in the b-cyclodextrins molecules attached to the surface of organosilicas, was proved. The interpretation of interaction peculiarities of mercury and cadmium nitrates with the synthesized b-cyclodextrin-containing silicas was given started from the theory of hard and soft acids and bases.

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References


Government sanitary standard and rules “Sanitary orders for drinking water, intended for human use” DSanPiN 2.2.4-171-10. Кyiv: Ministry of public health protection of Ukraine order N 400, 12.05.2010. Official Bulletin of Ukraine, 2010. N 51. (in Ukraine).

Kutsenko S.A. Basics of Toxicology. Saint-Petersburg: Foliant, 2004. (in Russian).

Scherbov D.P., Matveets M.A. Analytical Chemistry of Cadmium. Moscow: Nauka, 1973. (in Russian).

Amphlett C.B. Inorganic Ion Exchangers. Amsterdam: Elsevier, 1964.

Marhol M. Ion Exchangers in Analytical Chemistry. Their Properties and Use in Inorganic Chemistry. Prague: Academia, 1982.

Ionites in Chemical Technology. Eds. B.P. Nikol’skiy and P.G. Romankov. Leningrad: Khimiya, 1982. (in Russian).

Myasoedova G.V., Savvin S.B. Chelating Sorbents. Moscow: Nauka, 1984. (in Russian).

Tertykh V.A., Belyakova L.A. Chemical Reactions with Participation of Silica Surface. Kiev: Naukova Dumka, 1991. (in Russian).

Vansant E.F., Van Der Voort P., Vrancken K.C. Characterization and Chemical Modification on the Silica Surface. Amsterdam: Elsevier, 1995.

Jal P.K., Patel S., Mishra B.K. Talanta. 2004. 62. 1005. doi 10.1016/j.talanta.2003.10.028

Szejtli J. Chem. Rev. 1998. 98(5). 1743. DOI: 10.1021/cr970022c

Lehn J.M. Supramolecular Chemistry. Concepts and Perspectives. VCH Verlagsgesellschaft, 1995.

Steed J.W., Atwood J.L. Supramolecular Chemistry. John Wiley&Sons, 2000.

Iler R.K. The Chemistry of Silica: Solubility, Polymerization, Colloid and Surface Properties and Biochemistry of Silica. New York: Wiley-Interscience, 1979.

Kiselev A.V. Intermolecular Interactions in Adsorption and Chromatography. Moscow:Vysshaya Shkola, 1986. (in Russian).

Belyakova L.A., Kazdobin K.A., Belyakov V.N. et al. J. Colloid Interface Sci. 2005. 283. 488. doi 10.1016/j.jcis.2004.09.012

Belyakova L.A., Lyashenko D.Yu., Varvarin A.M. et al. Ukr. Chem. Journal. 2005. 71(8). 86. (in Russian).

Belyakova L.A., Varvarin A.M., Lyashenko D.Yu., Khora O.V. Ads. Sci. Technol. 2005. 23(9). 703. doi 10.1260/026361705776316596

Experimental Methods in Adsorption and Molecular Chromatography. Eds. A.V. Kiselev and V.P. Dreving. Moscow: MGU Publisher, 1973. (in Russian).

Belyakova L.A., Besarab L.N., Roik N.V. et al. J. Colloid Interface Sci. 2006. 294. 11. doi 10.1016/j.jcis.2005.06.081

Goldstein J.I., Yakowitz H. Practical Scanning Electron Microscopy. Electron and Ion Microprobe Analysis. New York:Plenum, 1975.

Schwarzenbach G., Flashka H. Die Komplexonometrische Titration. Stuttgard: Ferdinant Enke,Verlag, 1965.

Bagdasarov K.N., Kovalenko P.N., Shemyakina M.A. J. Analyt. Chem. 1968. 23(4). 515. (in Russian).

Langmuir I. J. Am. Chem. Soc. 1918. 40(9). 1361.

Freundlich H., Heller W.J. J. Am. Chem. Soc. 1939. 61(8). 2228.

Gupta S.S., Bhattacharyya K.G. J. Colloid Interface Sci. 2006. 295(1). 21. doi 10.1016/j.jcis.2005.07.073

Belyakova L.A., Lyashenko D.Yu., Shvets O.M. Russ. J. Phys. Chem. A. 2010. 84(4). 656. doi 10.1134/S0036024410040230

Belyakova L.A., Shvets O.M. Chemistry, Physics and Technology of Surface . 2010. 1(3). 274.

Schindler P., Kamber G.R. Helv. Chim. Acta. 1968. 51(7). 1781. doi:10.1002/hlca.19680510738

Fenelonov V.B. Introduction into Physical Chemistry of Formation of Supramolecular Structure of Adsorbents and Catalysts. Novosibirsk: SB RAS, 2004. (in Russian).

Belyakova L.A., Lyashenko D.Yu. Shvets O.M. Coll. Chemistry, Physics and Technology of Surface. 2009. 15. 80. (in Russian).

Belyakova L.A., Lyashenko D.Yu. J. Appl. Spectrosc. 2008. 75(3). 314. doi 10.1007/s10812-008-9047-0

Belyakova L.A., Lyashenko D.Yu., Shvets O.M. in Nanomaterials and Supramolecular Structures. Physics, Chemistry, and Applications. Eds: A.P. Shpak and P.P. Gorbyk. Springer, 2009. 247-258.

Dzyazko Yu.S., Belyakova L.А. Ukr. Chim. Zhurnal. 2009. 75(10). 77. (in Russian).

Dzyazko Yu.S., Belyakova L.А., Lyashenko D.Yu. Chemistry, Physics and Technology of Surface. 2011. 2(3). 242. (in Russian).

Pearson R.G. J. Chem. Educ. 1968. 45. 581. doi: 10.1021/ed045p581

Pearson R.G. J. Chem. Educ. 1968. 45(10). 643. doi: 10.1021/ed045p643

Marcus Y., Kamlet M. J., Taft R. W. J. Phys. Chem. 1988. 92. 3613. doi: 10.1021/j100323a057




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